C(H₂O)n
Carbohydrates in the cell membrane, like glycolipids and glycoproteins, are used for cell-to-cell communication.
They are types of carbohydrates.
Fructose
Pectin adds bulk and water to stools, helping them pass more easily through the intestines.
Starch in plants and glycogen in humans.
N-acetyl-D-glucosamine (NAG) units.
A furanose is a 5-membered, hemiketal structure, most important for ketose sugars like fructose.
Glycogen is made up of α-glucose units.
Reducing sugar.
Reducing sugar.
A glycosidic bond is formed by condensation and broken by hydrolysis.
Hexoses, such as glucose, fructose, and galactose.
In the form of ATP.
They are used for cell-to-cell communication.
The test for starch is the Iodine Test, and a positive result is indicated by a blue-black or purple color.
Serums.
They are constituents; DNA contains deoxygenated ribose and RNA contains ribose.
By the addition of functional groups.
Amylopectin is a branched component of starch, broken down by enzymes to release glucose when needed by the plant, has a larger surface area due to branching, and constitutes 80-85% of stored starch.
Cellulose (books, cotton in clothes, wood) and starch (bread, pasta, potatoes, rice, corn, beans, peas).
Two glucose molecules.
The bond is called a glycosidic bond.
Cellulose.
Cellobiose has beta 1,4 glycosidic linkages, while maltose has alpha 1,4 glycosidic bonds.
Atoms to the left of the anomeric carbon are projected up axially or up equatorially.
Monosaccharides made up of 5 carbon atoms, e.g., ribose, deoxyribose, ribulose.
Flavin adenine dinucleotide
Alpha form of glucose.
Starch serves as the energy storage of plants, storing excess glucose.
The branching in glycogen is 3 times more frequent than in starch because humans need more energy and glucose, resulting in more glycogen storage.
Negative (blue), as there are no reducing sugars to oxidize.
Food and energy (from consumption) and structural material (e.g., cellulose in the cell wall of plants).
A Haworth projection is a method for representing the spatial arrangements of atoms within a carbohydrate, where all atoms to the bottom are projected forward and the other three sides above are projected to the back.
Simplest sugars with a single carbon chain.
3 to 9 carbon atoms.
Water-soluble, white crystalline solids.
Axial positions are straight lines going up or down in 3D space, whereas equatorial positions project towards the sides, either forward or back in 3D space.
AMP, ADP, and ATP
Beta form of glucose.
Starch is found in chloroplasts, seeds, and tubers/root crops such as turnips, carrots, and potatoes.
Glycogen is found in muscles, where it supplies glucose and energy to the muscles, and in the liver, where it supplies glucose for the entire body and other tissues.
Aldonic acid is a weak oxidizing agent that can only oxidize the C1 carbon.
Cellulose (cell wall of plants), starch (plants), and glycogen (animals).
Atoms to the right of the anomeric carbon are projected down axially or down equatorially.
Enantiomers are stereoisomers that are superimposable, mirror images of each other.
N-acetyl-β-D-glucosamine and D-glucoronate.
They are needed for the formation of polysaccharides and make up most of the food we ingest.
The hydroxyl group (-OH) starts at the left.
Amylose is unbranched, linear, readily digested, takes up less space, and constitutes 15-20% of stored starch in plants (up to 30%).
β (beta).
Beta 1,4 glycosidic linkage.
The number of carbon atoms.
Glyceraldehyde is used in the formation of glycerol, which is used in lipid formation.
It retains moisture.
Glucose
Pectin is found in fruits and is a major component of the middle lamella that binds cells together, also found in primary cell walls.
Glycogen, also known as 'animal starch,' serves as an energy reserve for animals, storing excess glucose.
An oxidizing agent is a reduced substance.
Straight chain = 1,4 linkages; Branched = 1,6 linkages.
In a beta-D-glucose Haworth projection, the OH group is up.
Tautomers are isomers that readily interconvert by relocating a proton when in equilibrium. An example is d-glucose and d-fructose.
Diastereomers are non-superimposable, non-mirror images of each other. They change at one or more points but are not mirrored.
C5H10O5
The Fischer projection is a way to draw long-chain molecules with several chiral carbons, shaped like a fishbone for convenience.
Chitin is the second most abundant polysaccharide, found in the rigid coating of exoskeletons of animals like shrimp.
Disaccharides formed by linking two monosaccharide units.
Monosaccharides can undergo oxidation-reduction reactions.
Glycans.
A chain that contains only one type of monosaccharide unit, e.g., cellulose, starch, and glycogen (all contain repeating units of glucose).
The darker the color, the higher the amount of reducing sugar present.
It is used for photosynthesis.
Hyaluronic acid.
They supply the carbon atoms of different macromolecules.
The hydroxyl group (-OH) starts at the right.
Heparin is found in green evacuated tubes and is used for arterial blood gases to prevent the blood from clotting immediately.
Chitin can trigger an allergy-like response in the immune system and is generally indigestible, though some people have chitinase to metabolize it.
Glucose and fructose.
No, polysaccharides are not sweet. The more sugars you put together, the less sweet they become.
Reduction produces sugar alcohols (polyhydroxy alcohols), such as glucitol, commonly known as sorbitol.
Atoms on the right side of a Fischer projection are represented as down in a Haworth projection.
In an alpha-D-glucose Haworth projection, the OH group is down.
Monosaccharides made up of 3 carbon atoms, e.g., glyceraldehyde and dihydroxyacetone.
Heparin is a highly sulfated polysaccharide used as an anticoagulant (blood thinner) for treating thrombotic events.
They are fibrous (straight chain), tasteless, and odorless, and are made up of β-glucose units.
A brick-red precipitate.
Galactose and glucose.
Aldaric acid is a strong oxidizing agent that oxidizes both ends (the 1st and last carbon).
α (alpha).
A polysaccharide that contains two or more types of monosaccharide units, e.g., glucose + galactose + maltose.
Carbon 5 will attack Carbon 1.
Alpha 1,6 linkages.
A pyranose is a 6-membered, hemiacetal (heterocyclic) structure.
A polymeric carbohydrate that contains many monosaccharide units covalently bonded to each other.
Alduronic acid oxidizes the C6 or last carbon and involves enzymes like amylase and lactase.
Atoms on the left side of a Fischer projection are represented as up in a Haworth projection.
Alpha 1,2 glycosidic linkages.
Maltose and lactose.
Glyceraldehyde 3-phosphate (G3P) is used in respiration and carbohydrate metabolism.
Ribose is needed in the synthesis of some coenzymes, such as NAD and NADP.
All monosaccharides and some disaccharides (maltose and lactose).
Non-reducing sugar.
A reducing agent is an oxidized substance, also known as reducing sugars, which can reduce other substances.
The configuration can be either α or β.
Monosaccharides.
Alpha 1,4 glycosidic bond.
It is called ‘chair’ because it resembles a chair toppled over to the back.
Stereoisomers have the same molecular formula but different configurations due to asymmetric/chiral carbons, resulting in different 3D arrangements.
Structural isomers are molecules with the same molecular formula but different bonding arrangements.
Optical isomers rotate the plane of polarized light. D-forms (dextro-rotatory) rotate light to the right, while L-forms (laevo-rotatory) rotate light to the left.
Epimers are a type of diastereomer that differ from each other only at one carbon, which cannot be the anomeric carbon.
Anomers differ in the position of the hydroxyl group attached to the anomeric carbon. They are often referred to as 'alpha' and 'beta' forms.
C
glycogen
retain
synovial
asymmetric/chiral
starch
N-acetyl-β-D-glucosamine, D-glucoronate
macromolecules
proton
beta
superimposable
Glycolipids, glycoproteins
serums
ATP
alpha
d-glucose, d-fructose
down
polarized
polyhydroxyaldehydes, polyhydroxyketones
sulfated
non-superimposable
laevo, left
blue-black, purple
flavin adenine dinucleotide
α-D-glucose
glucose
6, hemiacetal
6
deoxygenated
green
down, down
up, up
Iodine
oxidizing
reducing
80-85%
bread, pasta, potatoes, rice, corn
3, glyceraldehyde, dihydroxyacetone
disaccharides
up
galactose, glucose
5, hemiketal
up
C6
glycogen
cellulose, starch
1,4; 1,6
phosphate
anticoagulant
Β-glucose
stool bulking
oxidation-reduction
anomeric
molecular, bonding
branched
3
condensation, hydrolysis
respiration
beta
glycosidic
muscles
negative
C5H10O5
energy
down
alpha
galactose, glucose, fructose
1st, last
animal
α-glucose
one
glucose, fructose, galactose
glucose, fructose
middle lamella
dextro, right
polysaccharide
5, 1
allergy-like
C1
alpha
monosaccharide
entire
photosynthesis
AMP, ADP, ATP
beta
left
carbon, 3, 9
polysaccharides
unbranched, linear
Glucose
sorbitol
cellulose, starch, glycogen
cellulose, starch, glycogen
one
15-20%
brick-red
glycan
glycerol
N-acetyl-D-glucosamine (NAG)
right
polyhydroxy
cellulose
5, ribose, deoxyribose, ribulose
nicotinamide
hydroxyl
fruits
fishbone
Maltose, lactose
food, energy
smallest, sugars
two
water
coenzymes
books, cotton, wood
carbon
Hexoses